02290

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02290

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L-(−)-Malic acid

purum, ≥99.0% (T)

Synonym:(S)-(−)-2-Hydroxysuccinic acid, L-Hydroxybutanedioic acid
CAS Number:97-67-6
Linear Formula:HO2CCH2CH(OH)CO2H
Molecular Weight:134.09
Beilstein Registry Number:1723541
EC Number:202-601-5
MDL number:MFCD00064213

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Description

Other NotesPreparation of (S) 2-acetoxysuccinyl chloride1; Preparation of 1-mono-methyl malate2,3; Preparation of hydroxysuccinimide derivatives4; Stereoselective α-alkylation via dioxolanone5

Properties

gradepurum
assay≥99.0% (T)
optical activity[α]20/D −30±2°, c = 5.5% in pyridine
mp101-103 °C(lit.)
 103-106 °C

Safety

Personal Protective Equipmentdust mask type N95 (US), Eyeshields, Gloves
Hazard CodesXi
Risk Statements36/37/38
Safety Statements26-36
WGK Germany3

References

Cited Reference1. F. Johnson et al. J. Am. Chem. Soc. 104, 2190, (1982)
 2. M.J. Miller et al. J. Org. Chem. 47, 4928, (1982)
 3. S. Henrot et al. Synth. Commun. 16, 183, (1986)
 4. H. Niwa et al. J. Org. Chem. 52, 2941, (1987)
 5. D. Seebach et al. Tet. 40, 1313, (1984)
MerckMerck 13,5730
BeilsteinBeil. 3,IV,1123
referenceAldrich MSDS 1, 1153:D / Corp MSDS 1 (2), 2187:B / FT-IR 1 (1), 522:C / FT-IR 2 (1), 810:C / IR-Spectra (3), 306:A / IR-Spectra (2), 275:H / NMR-Reference 2 (1), 456:C / RegBook 1 (1), 567:L / Sigma FT-IR 1 (2), 694:A / Structure Index 1, 81:A:4